Not really, a Dark Knight/Ranger wouldn't really bring much to the party. First of all, Dark Knights have a horrible rating with bows, they do alright with a Crossbow but not for damage, more for an acid bolt or a bloody bolt. The ranger sub would really bring down the melee abilities compared to /Thief or /Warrior. The ranger is not a bad idea if you're camping a NM or something, but not for normal EXP parties.